中性子小角散乱は生きたままを見る分析技術<br>－重合反応を追跡する－

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  • 小泉 智
    （独）日本原子力研究開発機構量子ビーム応用研究部門

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  • Neutron is a Marvelous Probe to See the Living Things as it is Alive.<br>–Real Time & in-situ Observation on Living Polymerization–
  • 中性子小角散乱は生きたままを見る分析技術--重合反応を追跡する
  • チュウセイシ ショウカク サンラン ワ イキタ ママ オ ミル ブンセキ ギジュツ ジュウゴウ ハンノウ オ ツイセキ スル
  • Neutron is a Marvelous Probe to See the Living Things as it is Alive.<br>&ndash;Real Time & in-situ Observation on Living Polymerization&ndash;

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Small-angle neutron scattering was employed in order to perform a real time & in-situ observation on a polymerization-induced self-assembly process in in-vivo or in-vitro systems ; precise living anionic polymerization of polystyrene-b-polyisoprene, pre-irradiation radical polymerization of polystyrene onto a polytetrafluoroethylene film, and microbial or enzymatic polymerization of cellulose. The aim of these studies is to clarify self-organizations of macromolecular assemblies appeared in open non-equilibrium systems, which are exposed to external energy and mass flows induced by chemical reactions. The open non-equilibrium systems are believed to be important for understanding pattern formations not only in materials processing in industry but also in living things. Small-angle scattering observed for the systems was investigated according to the methods established for condensed matter physics (fractal and computational analyses), bridging with synthetic chemistry and molecular biology.

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