ポリエチレンの臭素化反応ならびにその生成物について

書誌事項

タイトル別名
  • STUDIES ON THE REACTION OF POLYETHYLEN WITH BROMINE AND THE PROPERTIES OF THIER RECTION PRODUCTS. (AND THE PRODUCTS)
  • ポリエチレン ノ シュウソカ ハンノウ ナラビニ ソノ セイセイブツ ニ ツイテ

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抄録

Fundamental experiments were carried out with high-pressured polyethylene in order to get rubberlike elastomer through bromination and other processes, and then to investigate some of the physical and chemical properties of the products thus obtained.<br>Since polyethylene is saturated hydrocarbon, it is stable chemically. But it can be changed into halide through the existence of peroxide catalyst or under the irradiation of ultraviolet ray, etc.<br>The experiments, therefore, were made by the following processes:<br>(1) After bromination, the conditions of the bromine contents of the products were considered.<br>(2) When polyethylene bromide was further treated in the current of N2 gas at high temperature, HBr. was confirmed to be was confirmed to be generated.<br>(3) The occurrence of double-bond and cross-linkage, etc. in the produced resin by the thermal reaction, was examined.<br>(4) Polyethylene bromide, after mixed directly with metallic oxide (for example, MgO), was vulcanized.<br>(5) Some of the physical and chemical properties of the vulcanized products were tested.

収録刊行物

  • 日本ゴム協会誌

    日本ゴム協会誌 36 (3), 290-294, 1963

    一般社団法人 日本ゴム協会

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