AUTOHESION OF RAW RUBBER

  • Yasuda G.
    Yokkaichi Copolymer Plant, Japan Synthetic Rubber Co., Ltd.
  • Ido S.
    Yokkaichi Copolymer Plant, Japan Synthetic Rubber Co., Ltd.

Bibliographic Information

Other Title
  • 部分的に改造したピックアップ式タックメーターによる粘着性の長時間測定
  • ブブンテキ ニ カイゾウ シタ ピックアップシキ タックメーター ニ ヨル ネンチャクセイ ノ チョウジカン ソクテイ
  • PART II SUPPLEMENTARY MEASUREMENTS TO PART I BY MODIFIED PICKUP TACKMETER

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Abstract

A Pickup tackmeter was partially modified to prolong the autohesion measurements on raw rubber samples up to the order of 103min. The dependence of the maximum tack strength, F, on the time of contact, tp, in the longer time region could always be approximated by the following empirical equation, <br>F=F0+(F-F0)(1-e-tp/τp).<br>Here F0 and F are the numerical parameters independent of tp. The constant, τp, which is a measure of the rate process of the autohesion, was found to be roughly proportional to the 3.4th power of the average molecular weight of the sample for SBR. This finding on τp would suggest that the mobility of rubber molecules is an important factor to the autohesion process.

Journal

  • NIPPON GOMU KYOKAISHI

    NIPPON GOMU KYOKAISHI 36 (12), 1089-1094, 1963

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

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