TMTDとジフェニルメタンの反応

書誌事項

タイトル別名
  • STUDIES ON TMTD (I)
  • TMTD ト ジフェニルメタン ノ ハンノウ
  • REACTION OF TMTD WITH DIPHENYLMETHANE

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抄録

Reaction of TMTD (tetramethylthiuram disulfide), diphenylmethane, zinc soap of fatty acid and zinc oxide at 140° gave zinc dimethyldithiocarbamate (I), fatty acid and smaller amounts of free sulfur, zinc sulfide and benzhydryl dimethyklithiocarbamate (II). The reaction involving the same ingredients at 100° gave tetramethylthiuram mono-sulfide and II besides I and fatty acid, but not free sulfur and zinc sulfide. A free radical mechanism is proposed temporarily to interpret the results.

収録刊行物

  • 日本ゴム協会誌

    日本ゴム協会誌 35 (11), 826-831, 1962

    一般社団法人 日本ゴム協会

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