書誌事項
- タイトル別名
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- Development of Novel Conductive Rubber Rollers using NBR/Polyether Electrolyte Blends with Nanoscale Sea-Island Phase Separation
- ナノソウ ブンリ コウゾウ オ ケイセイ スル NBR/ポリエーテルガタ デンカイシツ ブレンド ノ サクセイ ト シンキ ドウデン ゴムローラー エ ノ オウヨウ
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<p>For the development of antistatic rubber rollers, we prepared acrylonitrile-butadiene rubbers (NBR)/polyether-based electrolyte blends by mechanical mixing method with different polymerization conditions. The effects of different humidity environment and morphology on the ion-conductive behavior were revealed using DC conductivity measurement system and transmission electron microscopy (TEM). The TEM images showed that the nano-ordered phase separated structure in the blends is formed before the polymerization. The sea-island phase separated structure of the blends could be controlled by polymerization conditions. We also found that there is a crucial relation between the conductive behavior under different humidity conditions and morphology, and the micro-phase separated structure with 10-20 nm-size of polyether islands give rise to the decrease in the difference between conductivities measured in wet and dry conditions. We also prepared vulcanized or cross-linked NBR blends using sulfur or organic peroxide as polymerization initiator. The cross-linked blends with nano-ordered phase separated structure were obtained, which shows good antistatic performance even in the humid condition. In addition, we prepared a plot type rubber roller using the NBR/polyether-based electrolyte blend, and it worked well as an actual printer roller.</p>
収録刊行物
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- 日本ゴム協会誌
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日本ゴム協会誌 90 (2), 23-29, 2017
一般社団法人 日本ゴム協会
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詳細情報 詳細情報について
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- CRID
- 1390282681541188736
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- NII論文ID
- 130005529702
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- NII書誌ID
- AN00269207
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- ISSN
- 18840442
- 0029022X
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- NDL書誌ID
- 027986529
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可