-
- 福森 健三
- (株)豊田中央研究所 有機材料研究室
書誌事項
- タイトル別名
-
- Time-resolved XAFS Study on Crosslinking Reaction of Sulfur-based Rubber Compounds
- ジブンカツ XAFSホウ ニ ヨル イオウ カケハシ ハイゴウ ゴム ノ カケハシ ハンノウ カイセキ
- Time-Resolved XAFS Study on Crosslinking Reaction of Sulphur Based Rubber Compounds
この論文をさがす
説明
Crosslinking reaction of sulfur-based rubber compounds with sulfur, accelerators and zinc oxide (ZnO) as crosslinking agents was studied by a time-resolved X-ray adsorption fine structure (XAFS) method. The Zn K-edge XANES (X-ray absorption near-edge structure) spectra obtained during the process were properly decomposed into two components, assigned to ZnO and zinc sulfide (ZnS). The [ZnO]/[Zn] ratio was found to decrease with the increased amounts of sulfur and accelerators, or by the addition of surface active-carbon black. It was confirmed that the decreasing behavior of the amount of ZnO gives a good indicator of the crosslinking reaction by changing of ZnO into ZnS through the chemical reactions with sulfur-containing reagents.
収録刊行物
-
- 日本ゴム協会誌
-
日本ゴム協会誌 87 (3), 83-88, 2014
一般社団法人 日本ゴム協会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282681542557824
-
- NII論文ID
- 130004551512
-
- NII書誌ID
- AN00189720
-
- COI
- 1:CAS:528:DC%2BC2cXht1WmsbrP
-
- ISSN
- 18840442
- 14782405
- 0029022X
- 0307174X
-
- NDL書誌ID
- 025338579
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDLサーチ
- Crossref
- CiNii Articles
- OpenAIRE
-
- 抄録ライセンスフラグ
- 使用不可