Electron-transfer Reaction of Poly(ethylene oxide)-modified Pseudoazurin at Gold Electrodes Modified with Carboxylic Acid-terminated Alkanethiols

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  • NAKAMURA Nobuhumi
    Department of Biotechnology, Tokyo University of Agriculture and Technology
  • AOKI Michio
    Department of Biotechnology, Tokyo University of Agriculture and Technology
  • MORIKAWA Yuki
    Department of Biotechnology, Tokyo University of Agriculture and Technology
  • OHNO Hiroyuki
    Department of Biotechnology, Tokyo University of Agriculture and Technology
  • YAMAGUCHI Kazuya
    Department of Chemistry, Graduate School of Science, Osaka University
  • SUZUKI Shinnichiro
    Department of Chemistry, Graduate School of Science, Osaka University

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<p>Pseudoazurin from Achromobacter cycloclastes IAM 1013 was modified with poly(ethylene oxide) without denaturation. The redox response of the modified pseudoazurin was investigated by cyclic voltammetry. When the gold electrodes modified with carboxylic acid-terminated alkanethiols were used as working electrodes, the redox responses of the modified pseudoazurin were observed, although these thiols were not effective promoters for the unmodified (native) pseudoazurin.</p>

収録刊行物

  • Electrochemistry

    Electrochemistry 69 (12), 959-961, 2001-12-05

    公益社団法人　電気化学会

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