塩基性水系電解質における炭素材料の電気化学挙動

書誌事項

タイトル別名
  • Electrochemical behaviors of carbonaceous materials in alkaline aqueous solutions
  • エンキセイ スイケイ デンカイシツ ニ オケル タンソ ザイリョウ ノ デンキ カガク キョドウ

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抄録

<p>The electrochemical behavior of some carbonaceous materials in alkaline aqueous solutions are discussed. Carbon black, which is mixed as an electro-conductive additive, has a catalytic activity for the oxygen reduction reaction (ORR) in alkaline solutions. Following the initial 2-electron reduction on carbon, metal-oxide catalysts decompose the intermediate HO2 to form OH and O2. Graphite forms graphite intercalation compounds (GICs) containing OH in alkaline solutions with a high ionic strength, while the formation of GICs was not observed in the solutions with a low ionic strength.</p>

収録刊行物

  • 炭素

    炭素 2018 (283), 118-123, 2018-07-15

    炭素材料学会

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