書誌事項
- タイトル別名
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- Toward a More Accurate Understanding of Impedance Behaviors of Randles-type Equivalent Circuits
- Randlesガタ トウカ カイロ インピーダンス ノ フクソ ヘイメン ジョウ ノ キセキ ニ カンスル ジュウライ ノ キジュツ ニ タイスル イチ ギモンテン
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説明
<p>On the complex plane, an impedance of a Randles-type equivalent circuit, which is commonly used for the analysis of an electrochemical impedance, traces a semicircle originated from the parallel connection of the charge-transfer resistance (Rct) and the double-layer capacitance (Cdl), and a 45-degree line originated from the Warburg element (ZW). It is often mentioned that there is an “overlap” between the semicircle and the extrapolation of the 45-degree line, and mathematically it has a length of 2⋅σ 2⋅Cdl. Although this is correct, to emphasize the existence of such an “overlap” may mislead the analysis, since its magnitude is extremely small compared with the size of the semicircle, when the figures of the semicircle and line are visibly separated from each other.</p>
収録刊行物
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- Review of Polarography
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Review of Polarography 64 (2), 91-96, 2018-10-17
日本ポーラログラフ学会
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詳細情報 詳細情報について
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- CRID
- 1390282763059798144
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- NII論文ID
- 130007499252
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- NII書誌ID
- AA00817694
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- ISSN
- 18847692
- 00346691
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- NDL書誌ID
- 029318615
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDLサーチ
- Crossref
- CiNii Articles
- OpenAIRE
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- 抄録ライセンスフラグ
- 使用不可