Close-Packed Lattice in Sphere-Forming Block Copolymer/Block Copolymer Blends

DOI Web Site Web Site 21 References
  • TAKAGI Hideaki
    Photon Factory, Institute of Materials Structure Science, High Energy Accelerator Research Organization Department of Materials Structure Science, School of High Energy Accelerator Science, Graduate University for Advanced Studies
  • YAMAMOTO Katsuhiro
    Frontier Research Institute of Materials Science, Nagoya Institute of Technology Graduate School of Engineering, Department of Life Science & Applied Chemistry, Nagoya Institute of Technology

Bibliographic Information

Other Title
  • ブロック共重合体/ブロック共重合体ブレンドの球状ミクロドメインが作る最密充填格子
  • ブロック キョウ ジュウゴウタイ/ブロック キョウ ジュウゴウタイ ブレンド ノ キュウジョウ ミクロドメイン ガ ツクル サイミツジュウテン ゴウシ

Search this article

Description

<p>The phase behavior in binary mixtures of block copolymers was investigated using synchrotron small angle X-ray scattering. Polystyrene-polyisoprene block copolymers (SI) have equal length of the polyisoprene blocks, whereas the length of minority polystyrene blocks differs. In the blend sample with the weight fraction of long SI of 10 wt%, disordered spheres was formed, whereas closely packed spheres in face-centered cubic lattice was observed for the sample with 30 wt%. It was also found that the blend with 50 wt% showed cylindrical microdomains. Thus, the close-packed lattice was observed as a stable phase in block copolymer/block copolymer blends.</p>

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 76 (2), 157-162, 2019-03-25

    The Society of Polymer Science, Japan

References(21)*help

See more

Related Projects

See more

Keywords

Details 詳細情報について

Report a problem

Back to top