エチレン・酢酸ビニル共重合樹脂（EVA）／超低密度ポリエチレン樹脂（V-LDPE）ブレンド架橋発泡製品に対する組成比率の定量分析

星野 裕樹, 原野 健一, 西脇 剛史

doi:10.2324/gomu.92.363

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タイトル別名

Quantitative Analysis for Estimating the Content Ratio of Ethylene Vinyl Acetate Copolymer (EVA)/Very Low Density Polyethylene (V-LDPE) Blended Foam
エチレン・サクサンビニルキョウジュウゴウジュシ(EVA)/チョウテイミツドポリエチレンジュシ(V-LDPE)ブレンドカキョウハッポウセイヒンニタイスルソセイヒリツノテイリョウブンセキ

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説明

<p>Recently, ethylene vinyl acetate (EVA) and very low density polyethylene (V-LDPE) blended foam (EVA/V-LDPE-foam) used in various industrial fields has been studied in order to improve the mechanical properties such as lightness and cushioning. The content ratio of EVA and V-LDPE was one of the important factors to control mechanical properties. The determination of the ratio of the above was desired from the view of quality control. The ratio could be determined through comparison between the content of vinyl acetate of non-linked EVA(VA wt%_N) and EVA/polyethylene (PE) foam (VA wt%_F). However, it was difficult to determine VA wt%_N by the conventional analytical techniques. In this study, a trace amount of non-cross-linked EVA in the cross-linked foam is focused on the determination of VA wt%_N. Separation of non-linked EVA was attempted by using solubility-difference between EVA and V-LDPE which were extracted from the foam to 10 vol% acetonitrile in chloroform solution. As a result, non-linked EVA was separated from non-linked components including a trace amount of V-LDPE by elution-time-difference. VA wt%_N was estimated by Fourier-transform infrared spectroscopy (FT-IR) and the content ratio was determined through comparison between VA wt%_N and VA wt%_F.</p>

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日本ゴム協会誌

日本ゴム協会誌 92 (10), 363-369, 2019

一般社団法人日本ゴム協会

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