電気化学計測と量子化学計算を基盤とした有機電子移動化学の基礎研究

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  • Basic Study on Organic Electron Transfer Reactions by Electrochemistry Combined with Quantum Chemical Calculations
  • デンキ カガク ケイソク ト リョウシ カガク ケイサン オ キバン ト シタ ユウキ デンシ イドウ カガク ノ キソ ケンキュウ

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<p>This review summarizes the results of the author's basic research on organic electrochemistry conducted at Gifu Pharmaceutical University over about 40 years. After completing graduate school, the author became a research associate in Prof. Tanekazu Kubota's laboratory and started research on molecular spectroscopy in 1983. After Prof. Kubota retired in 1989, the author continued investigations in the field of organic electrochemistry as an independent researcher. At that time, a research environment in which ab initio molecular orbital calculations can be used as an analytical tool for experimental research was developed, and the author commenced research on organic electrochemistry combined with quantum chemical calculations as a lifework. The author's research topics were basic research on the molecular theory of redox potentials of organic molecules, molecular design of functional molecules, intermolecular interactions of organic molecules involving electron transfers and electron transfer systems composed of bioactive quinones, and analytical application research based on the basic electrochemistry. In this review article, the essence of the research results is introduced while reflecting on the existing situation at the time of the research. The author concludes the review by expressing gratitude to all colleagues for supporting the research in the author's laboratory.</p>

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  • 薬学雑誌

    薬学雑誌 141 (7), 911-925, 2021-07-01

    公益社団法人 日本薬学会

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