Photoaddition Reaction of Methyl 2,4-Dioxopentanoate with Chloroprene
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- Hatsui Toshihide
- Institute of Advanced Material Study Kyushu University
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- Hashiguchi Tomokazu
- Graduate School of Engineering Sciences Kyushu University
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- Takeshita Hitoshi
- Tohwa University
Bibliographic Information
- Other Title
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- Photoaddition Reaction of Methyl 2 4 Di
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Abstract
The photoaddition reaction of methyl 2,4-dioxopentanoate with chloroprene gave two de Mayo type adducts, methyl 3-(1-chlorovinyl)-2, 6-dioxoheptanoate and methyl 3-chloro-2, 6-dioxo-3-vinyl-heptanoate. No regio isomers, 4-substituted esters, were observed. The photoadducts were converted to cyclohexenones and the selectivity of photoaddition was discussed.
Journal
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- 九州大学機能物質科学研究所報告
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九州大学機能物質科学研究所報告 11 (2), 83-85, 1997-12-15
Institute of Advanced Material Study Kyushu University
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Details 詳細情報について
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- CRID
- 1390290699812237056
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- NII Article ID
- 110006177520
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- NII Book ID
- AN10060378
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- ISSN
- 09143793
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- DOI
- 10.15017/7869
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- HANDLE
- 2324/7869
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- NDL BIB ID
- 4364921
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- Text Lang
- en
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- Data Source
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- JaLC
- IRDB
- NDL
- CiNii Articles
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- Abstract License Flag
- Allowed