Practical Procedures for Hydrosilylation of Ketones and Silane-induced Ring-opening Polymerization of Cyclic Ethers by Prior Activation of the Cluster Catalyst by Hydrosilanes : Improved Synthetic Procedures and Mechanistic Implication on the Catalytically Active Species
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- Matsubara Kouki
- Institute of Advanced Material Study Kyushu University
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- Iura Takafumi
- Graduate School of Engineering Sciences Kyushu University
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- Maki Tomoyuki
- Graduate School of Engineering Sciences Kyushu University
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- Terasawa Jun-ichi
- Graduate School of Engineering Sciences Kyushu University
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- Nagashima Hideo
- Institute of Advanced Material Study Kyushu University
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Abstract
Pre-activation of (μ_2,η^2:η^3:η^5-acenaphthylene)Ru_3(CO)_7 (1) by hydrosilanes in a small amount of dioxane provides novel convenient and useful procedures for hydrosilylation of carbonyl compounds and silane-induced ring-opening polymerization of cyclic ethers and a cyclic siloxane. The initial step of the catalytic cycle was investigated by NMR detection of products formed by the oxidative addition ofhydrosilanes to 1. A possibility for the involvement of cluster species in the catalytic cycle is discussed.
Journal
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- 九州大学機能物質科学研究所報告
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九州大学機能物質科学研究所報告 15 (2), 183-188, 2001-12-14
Institute of Advanced Material Study Kyushu University
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Details 詳細情報について
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- CRID
- 1390290699813121792
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- NII Article ID
- 110006177596
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- NII Book ID
- AN10060378
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- ISSN
- 09143793
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- DOI
- 10.15017/7948
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- HANDLE
- 2324/7948
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- NDL BIB ID
- 6065832
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- Text Lang
- en
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- Data Source
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- JaLC
- IRDB
- NDL
- CiNii Articles
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- Abstract License Flag
- Allowed