New Developments in solvent reduced Wittig olefination reactions with stabilized Phosphoranes

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  • Thiemann Thies
    Interdisciplinary Graduate School of Engineering Sciences, Department of Molecular and Material Sciences
  • Watanabe Masataka
    Interdisciplinary Graduate School of Engineering Sciences, Department of Molecular and Material Sciences
  • Iniesta Jesus
    Department of physical Chemistry, University of Alicante, Alicante, Spain

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Wittig olefination reactions under solventless and solvent-reduced reaction conditions are discussed. The authors have found that fluorobenzaldehydes such as pentafluorobenzaldehyde react even with the stabilized acetylmethylidenetriphenyl- and benzoylmethylidenetriphenylphosphoranes in solventless reaction systems.

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