Stereodivergent Synthesis of Chiral Silacyclopentanes
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- KUROO Akihiro
- Department of Mokecular and Material Sciences, Interdisciplinary Graduate School of Engineering, Kyushu University : Master's Program
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- YOSHIHIRO Daisuke
- Department of Mokecular and Material Sciences, Interdisciplinary Graduate School of Engineering, Kyushu University : Master's Program
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- IGAWA Kazunobu
- Department of Applied Molecular Chemistry, Institute for Materials Chemistry and Engineering, Kyushu University
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- TOMOOKA Katsuhiko
- Department of Applied Molecular Chemistry, Institute for Materials Chemistry and Engineering, Kyushu University
Bibliographic Information
- Other Title
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- キラルシラシクロペンタン類の立体分岐合成
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Description
A variety of chiral silacyclopentanes having asymmetric silicon were synthesized based on the stereospecific substitution at C4 carbon of silacyclopentenols. Mitsunobu reaction and Tsuji-Trost reaction of silacyclopentenols provided substitution products with inversion and retention of C4 stereochemistry, respectively. The thus obtained substitution products can be converted into novel silacyclopentane amine, and carboxylic acids in stereospecific manner.
Journal
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- 九州大学大学院総合理工学報告
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九州大学大学院総合理工学報告 42 (2), 18-21, 2021-02
Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
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Details 詳細情報について
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- CRID
- 1390290700431627136
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- NII Article ID
- 120007053158
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- NII Book ID
- AA1147319X
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- DOI
- 10.15017/4479148
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- HANDLE
- 2324/4479148
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- Text Lang
- ja
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- Article Type
- departmental bulletin paper
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- Data Source
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- JaLC
- IRDB
- CiNii Articles
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- Abstract License Flag
- Allowed