Stereodivergent Synthesis of Chiral Silacyclopentanes

DOI HANDLE Open Access
  • KUROO Akihiro
    Department of Mokecular and Material Sciences, Interdisciplinary Graduate School of Engineering, Kyushu University : Master's Program
  • YOSHIHIRO Daisuke
    Department of Mokecular and Material Sciences, Interdisciplinary Graduate School of Engineering, Kyushu University : Master's Program
  • IGAWA Kazunobu
    Department of Applied Molecular Chemistry, Institute for Materials Chemistry and Engineering, Kyushu University
  • TOMOOKA Katsuhiko
    Department of Applied Molecular Chemistry, Institute for Materials Chemistry and Engineering, Kyushu University

Bibliographic Information

Other Title
  • キラルシラシクロペンタン類の立体分岐合成

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Abstract

A variety of chiral silacyclopentanes having asymmetric silicon were synthesized based on the stereospecific substitution at C4 carbon of silacyclopentenols. Mitsunobu reaction and Tsuji-Trost reaction of silacyclopentenols provided substitution products with inversion and retention of C4 stereochemistry, respectively. The thus obtained substitution products can be converted into novel silacyclopentane amine, and carboxylic acids in stereospecific manner.

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Details 詳細情報について

  • CRID
    1390290700431627136
  • NII Article ID
    120007053158
  • NII Book ID
    AA1147319X
  • DOI
    10.15017/4479148
  • HANDLE
    2324/4479148
  • Text Lang
    ja
  • Data Source
    • JaLC
    • IRDB
    • CiNii Articles
  • Abstract License Flag
    Allowed

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