キラルシラシクロペンタン類の立体分岐合成

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Abstract

A variety of chiral silacyclopentanes having asymmetric silicon were synthesized based on the stereospecific substitution at C4 carbon of silacyclopentenols. Mitsunobu reaction and Tsuji-Trost reaction of silacyclopentenols provided substitution products with inversion and retention of C4 stereochemistry, respectively. The thus obtained substitution products can be converted into novel silacyclopentane amine, and carboxylic acids in stereospecific manner.

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