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- 石谷 治
- 東京工業大学理学院化学系
書誌事項
- タイトル別名
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- Researches on Photofunctional and Photocatalytic Chemistry of Metal Complexes as Core Materials
抄録
<p>We found the following new photochemical reactions and photophysical properties of transition metal complexes: (1) photochemical formation of Ru(II) hydride complexes, (2) photochemical ligand substitution reactions of the Re(I)diiminetricarbonyl complexes, and (3) control of photophysical and electrochemical properties of metal complexes by introducing p-p interaction between ligands. Application of these reactions and photophysical properties of transition metal complexes enabled us to synthesize new photofunctional metal-complex oligomers and polymers, and to develop efficient, durable, and highly selective photocatalysts for hydride reduction of NAD(P)+ models and CO2 reduction. We also succeeded construction of new photofunctional hybrids of the metal-complex photocatalysts with various solid materials, i.e. semiconductor-particle photocatalysts, p-type semiconductor electrodes, and mesoporous organosilica, which can drive photocatalytic reduction of CO2 via Z-scheme electron transfer, photocatalytic CO2 reduction by using water as a reductant and visible light as energy, and lightenergy accumulation for photocatalytic CO2 reduction, respectively.</p>
収録刊行物
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 79 (0), 3-24, 2022-06-06
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390292706102401920
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- ISSN
- 18831737
- 18826954
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可