Mass-Spectroscopic Studies on Ion-Molecule Reactions of Ar_2^+, N_3^+, and N_4^+ Cluster Ions with Simple Aliphatic Hydrocarbons at Thermal Energy

DOI 機関リポジトリ (HANDLE) オープンアクセス
  • 辻 正治
    Institute for Materials Chemistry and Engineering, and Research and Education Center of Green Technology, Kyushu University Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering, Kyushu University
  • 河野 裕之
    Department of Applied Science for Electronics and Materials, Interdisciplinary Graduate School of Engineering, Kyushu University : Graduate Student
  • 宇都 慶子
    Institute for Materials Chemistry and Engineering, and Research and Education Center of Green Technology, Kyushu University
  • 林 潤一郎
    Institute for Materials Chemistry and Engineering, and Research and Education Center of Green Technology, Kyuhu University Department of Applied Science for Electronics and Materials, Interdisciplinary Graduate School of Engineering, Kyushu University
  • 辻 剛志
    Department of Materials Science, Shimane University

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説明

Ion-molecule reactions of Ar_2^+, N_3^+, and N_4^+ cluster ions with CH_4, C_2H_2, C_2H_4, and C_2H_6 have been studied by using a thermal ion-beam apparatus. Rate constants were determined and compared with those obtained from Langevin theory. Rate constants of the Ar_2^+ + C_2H_2, Ar_2^+ + C_2H_4, and N_3+ + C_2H_6 reactions, which have not been measured, were determined to be 1.4, 8.1, and 3.6 × 10^<-10> cm3 s^-1, respectively. These values correspond to 14%, 74%, and 28% of calculated rate constants from Langevin theory, respectively.

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詳細情報 詳細情報について

  • CRID
    1390293015559054080
  • NII書誌ID
    AA1147319X
  • DOI
    10.15017/4795521
  • HANDLE
    2324/4795521
  • ISSN
    13467883
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • IRDB
  • 抄録ライセンスフラグ
    使用可

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