Thermodynamic and Rheological Properties of Ionic Gels Formed by Fluorine-containing Phenyl Benzoate Derivatives That Exhibit Liquid Crystallinity
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- Matsumoto Kenta
- Graduate School of Sciences and Technology for Innovation, Yamaguchi Univ.
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- Tomarino Tatsuya
- Graduate School of Sciences and Technology for Innovation, Yamaguchi Univ.
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- Yamaguchi Junya
- Graduate School of Sciences and Technology for Innovation, Yamaguchi Univ.
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- Kanetada Kotaro
- Graduate School of Sciences and Technology for Innovation, Yamaguchi Univ.
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- Morita Yuki
- Advanced Technology Institute, Yamaguchi Univ.
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- Okamoto Hiroaki
- Graduate School of Sciences and Technology for Innovation, Yamaguchi Univ.
Bibliographic Information
- Other Title
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- 液晶性を示す含フッ素安息香酸フェニル誘導体で形成したイオンゲルの熱力学特性およびレオロジー特性
Abstract
<p>In our previous work, it was found that some rod-shaped low molecular compounds containing perfluoroalkyl group at a terminal position exhibited smectic A phase in bulk state and gelated several organic solvents and/or ionic liquids. In this work, two types of fluorine-containing phenyl benzoate derivatives which changed the orientation of ester group were synthesized, and it was considered that the correlation between liquid crystallinity and gelation with [BMIM][TFSA] from the thermodynamic properties, microscope observation, and rheological properties. As the results of them, the 5wt% gels formed by {4-[2-(perfluorohexyl)]ethylsulfanyl}phenyl 4-(octyloxy)benzoate exhibited thixotropy and observed micelle-like texture by polarized microscope.</p>
Journal
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- Proceedings of Japanese Liquid Crystal Society Annual meeting
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Proceedings of Japanese Liquid Crystal Society Annual meeting 2022 (0), PC13-, 2022
THE JAPANESE LIQUID CRYSTAL SOCIETY
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Details 詳細情報について
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- CRID
- 1390296288050912000
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- ISSN
- 24325988
- 18803490
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- Text Lang
- ja
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- Data Source
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- JaLC
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- Abstract License Flag
- Disallowed