書誌事項
- タイトル別名
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- カシコウ オ キュウシュウ スル タカク ヒドリド サクタイ ノ セッケイ ト ヒカリ ハンノウセイ
- Design of Visible-Light Sensitive Multinuclear Hydride Complexes and their Reactivities
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抄録
type:Article
Dinuclear iridium polyhydride complexes bearing diphosphine ligands were synthesized and characterized for visible-light sensitive photocatlysis, such as CO_2 hydrogenation and hydrogen production. These complexes can be synthesized in high yields in two steps from a mononuclear cationic iridium complex, [Ir(cod)_2]BF_4, as a precursor. The structures of the complexes were unambiguously determined on the basis of single-crystal X-ray diffraction studies. One of the complexes showed favorable catalytic activity for CO_2 hydrogenation under low pressure conditions compared with the existing mononuclear catalysts. The catalytic activity was significantly higher under photoirradiation (λ = 395 nm), suggesting acceleration of the reaction by light. DFT calculations were conducted to elucidate the effect of light toward these polyhydride complexes.
identifier:http://repository.seikei.ac.jp/dspace/handle/10928/1588
収録刊行物
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- 成蹊大学理工学研究報告 = The journal of the Faculty of Science and Technology, Seikei University
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成蹊大学理工学研究報告 = The journal of the Faculty of Science and Technology, Seikei University 59 (1・2), 5-8, 2022-12-01
成蹊大学理工学部
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詳細情報 詳細情報について
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- CRID
- 1390296530912979840
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- NII書誌ID
- AA1203510X
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- ISSN
- 18802265
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- NDL書誌ID
- 032790167
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- IRDB
- NDL