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- 谷藤 一樹
- 京都大学 化学研究所
書誌事項
- タイトル別名
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- Studies on Biosynthesis and Catalysis of Metal-Sulfur Clusters
抄録
<p>Transition metal-sulfur clusters are ubiquitous as enzymatic cofactors and play critical roles in various molecular transformations. Their synthetic counterparts have been studied with a significant focus on structural and spectroscopic modeling in the past 50 years. However, applications of this class of compounds for other purposes remain limited. In this context, we have been working on applying synthetic metal-sulfur clusters to biochemical analysis and catalysis with great interest in the enzymatic N2-reducing cluster (FeMoco). Synthetic clusters function as artificial cofactors of enzymes. The resultant reconstituted proteins can perform catalytic reduction using a natural electron transfer system or help analyze an unidentified intermediate involved in the biosynthesis of FeMoco. In addition, we developed catalytic reduction reactions of inert small molecules (e.g. CO, CO2, and N2) promoted by synthetic clusters. This account overviews the series of research to deliver a brief perspective of the functional aspect of the synthetic metal-sulfur clusters.</p>
収録刊行物
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 81 (0), 58-65, 2023-05-31
錯体化学会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390297128795242240
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- ISSN
- 18831737
- 18826954
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
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- 抄録ライセンスフラグ
- 使用不可