Multi-network System including Dynamic and Static Covalent Bonds “Coexistence between Thermoplasticity and Creep Resistance” 1 Hydrogen Bond-1

DOI Web Site 38 References
  • CHINO Keisuke
    Resin Treatment & Enginnering Group, HPM R&D Dept., High Performance Materials Company, ENEOS Corporation

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Other Title
  • 動的結合と静的共有結合を含む マルチネットワークシステム「熱可塑性と耐クリープ性の両立」1　水素結合 -1

Abstract

<p>In general, rubber has a weak interaction between molecular chains, so if it is not crosslinked, it will flow and cannot withstand actual use. Covalent crosslinked rubber has high mechanical properties due to the strong bonding force of crosslinking, but it is difficult to reshape and recycle because of the difficulty to cleave the crosslink. On the other hand, thermoplastic elastomers use physical interactions between molecular chains (physical crosslinking) to suppress fluidity and express physical properties. Therefore, although it can be reshaped by disconnecting the physical crosslink due to heat, it lacks heat resistance (creep resistance). Heat resistance (creep resistance) is very important in industrial materials, but thermoplasticity and heat resistance have a trade-off relationship. As an attempt to break this trade-off, many studies have been reported to use dynamic bonds such as hydrogen bonds, ionic bonds, and dynamic covalent bonds for crosslinking. However, this trade-off has not been resolved. In recent years, for the purpose of improving heat resistance and creep resistance, attempts have been made to introduce static covalent bonds to dynamic bonding crosslinks, which will be explained in this lecture.</p>

Journal

  • NIPPON GOMU KYOKAISHI

    NIPPON GOMU KYOKAISHI 97 (1), 3-8, 2024

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

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