Intermolecular Interactions Induced by Full Fluorination: Molecular Recognition of Solid Materials Using Opposite Quadrupole Moment

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  • HORI Akiko
    Graduate School of Engineering and Science, Shibaura Institute of Technology

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  • フッ素が拓く分子間相互作用　四重極モーメントを活用した分子認識と固体材料
  • フッソ ガ ヒラク ブンシ カン ソウゴ サヨウ シジュウキョク モーメント オ カツヨウ シタ ブンシ ニンシキ ト コタイ ザイリョウ

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<p>Fluorine is a unique substituent that dramatically changes the intramolecular electron withdrawing nature and intermolecular interactions of aromatic materials without significantly changing their color or molecular structure. Herein, we introduce the quadrupole moments of aromatic compounds and the corresponding fluorinated compounds and discuss molecular recognitions of non-polar compounds, such as benzene and carbon dioxide, in non-porous crystals of fully fluorinated coordination complexes for their application to solid materials.</p>

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