Electronic Structure of the VO Film Grown on Ag(100): Resonant Photoelectron Spectroscopy Study
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- Sugizaki Yuichi
- Department of Chemistry, Rikkyo University
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- Motoyama Hiroki
- Department of Chemistry, Rikkyo University
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- Edamoto Kazuyuki
- Department of Chemistry, Rikkyo University
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- Ozawa Kenichi
- Department of Chemistry, Tokyo Institute of Technology
説明
<p>The electronic structure of the VO film grown on Ag(100) has been studied by photoelectron spectroscopy (PES) utilizing synchrotron radiation. The Ag(100) surface covered by the VO film formed by V deposition in O2 at 3.7 × 10−9 Torr and subsequent annealing at 450°C gave a (1 × 1) LEED pattern. In the PES spectra for the (1 × 1) VO film, the conduction band mostly composed of V 3d-components was observed at 0—2.5 eV. The valence band mostly composed of O 2p-components was formed overlapping with the substrate Ag 4d band, and the analysis of the resonant PES spectra revealed that the band existed at 4—10 eV. Both of the PES spectra for the VO film at room temperature and for that cooled to 4.86 K showed a clear cut-off at the Fermi edge, implying that the (1 × 1) VO film has a metallic electronic structure when the temperature is higher than 4.86 K. [DOI: 10.1380/ejssnt.2018.236]</p>
収録刊行物
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- e-Journal of Surface Science and Nanotechnology
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e-Journal of Surface Science and Nanotechnology 16 (0), 236-241, 2018-06-07
公益社団法人 日本表面真空学会
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詳細情報 詳細情報について
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- CRID
- 1390564237990781824
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- NII論文ID
- 130007384804
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- ISSN
- 13480391
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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- JaLC
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