Influence of tetragonality on crystal orientation induced by a strong magnetic field and on the piezoelectric properties of the (Bi0.5,Na0.5)1−xBaxTiO3 ceramic system

  • TANAKA Satoshi
    Department of Materials Science and Technology, Nagaoka University of Technology
  • SANO Keisuke
    Department of Materials Science and Technology, Nagaoka University of Technology
  • HARADA Tomohiro
    R & D Center, Taiyo Yuden Co. Ltd
  • SHIMIZU Hiroyuki
    R & D Center, Taiyo Yuden Co. Ltd
  • DOSHIDA Yutaka
    Division of Electrical and Electronic Engineering, Department of Innovative Engineering, Ashikaga University

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タイトル別名
  • Influence of tetragonality on crystal orientation induced by a strong magnetic field and on the piezoelectric properties of the (Bi<sub>0.5</sub>, Na<sub>0.5</sub>)<sub>1−</sub><i><sub>x</sub></i>Ba<i><sub>x</sub></i>TiO<sub>3</sub> ceramic system

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説明

Crystal-oriented (Bi0.5, Na0.5)1−xBaxTiO3 (BNBT), (x = 0.1–0.25) ceramics with a perovskite crystal structure were prepared by colloidal processing in a strong rotating magnetic field with the aim of improving their piezoelectric properties. The advantages of increasing the amount of Ba in these ceramics are twofold; specifically, this will lead to anisotropic crystal lattices and it will also increases the tetragonality. The crystal-oriented BNBT (x = 0.1–0.25) ceramics were prepared by using a rotating magnetic field to orient the a- and c-axes of the crystal in the powder compact. The degree of orientation also increased with the tetragonality. The phase transformation that occurred above Curie temperature during sintering redistributed the c-axis-oriented structure along both the a- and c-axes. Again, the c-axis orientation was enhanced by electrical field polarization. The piezoelectric d33 constant, which depended on the Ba content, achieved a maximum value of 122 pC N−1 at a Ba content of 15 mol %.

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