Solid oxide fuel cell using a H<sub>2</sub> fuel/CO<sub>2</sub> oxidant gas system
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- MIYAZAKI Yuta
- Department of Chemistry, Biotechnology, and Chemical Engineering, Kagoshima University
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- SHIMONOSONO Taro
- Department of Chemistry, Biotechnology, and Chemical Engineering, Kagoshima University
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- HIRATA Yoshihiro
- Department of Chemistry, Biotechnology, and Chemical Engineering, Kagoshima University
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- SAMESHIMA Soichiro
- Department of Chemistry, Biotechnology, and Chemical Engineering, Kagoshima University
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- YAMAJI Katsuhiko
- Fuel Cell Materials Group, Research Institute for Energy Conservation, National Institute of Advanced Industrial Science and Technology (AIST)
Abstract
<p>This paper reports the performance of a solid oxide fuel cell with yttria-stabilized zirconia (YSZ) electrolyte, Ni–YSZ anode and (La0.8Sr0.2)0.95MnO3 (LSM) cathode or RuO2–YSZ cathode using air oxidant or a CO2 oxidant and a H2 fuel with 3% H2O at 600–800°C. The power density was higher for air oxidant than for a CO2 oxidant. The measured power density was associated with the reduction of CO2 gas to solid carbon for the RuO2–YSZ cathode. In the cell with the LSM cathode, a CO2 oxidant was reduced to the mixed state of CO molecules and solid carbon. The reactivity of O2 or CO2 molecules in their mixed oxidant gas system for the YSZ cell with the LSM cathode changed drastically at 50–70 vol % CO2 in the O2–N2–CO2 gas system. It is possible to produce an electric power and to reduce CO2 gas into solid carbon at the same time during the operation of a solid oxide fuel cells using a CO2 oxidant.</p>
Journal
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 126 (10), 777-783, 2018-10-01
The Ceramic Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390564238027094016
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- NII Article ID
- 130007491121
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- ISSN
- 13486535
- 18820743
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed