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Photocatalytic reduction of oxidative potential of particulate matter 2.5 (PM<sub>2.5</sub>)
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- MISAWA Kazuhiro
- Graduate School of Earth and Environmental Sciences, Tokai University
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- SOHARA Koki
- Graduate School of Science, Tokai University
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- KUMAI Yuki
- Graduate School of Science, Tokai University
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- KUSUKUBO Yuki
- Graduate School of Science, Tokai University
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- SEKINE Yoshika
- Graduate School of Earth and Environmental Sciences, Tokai University
Bibliographic Information
- Other Title
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- 光触媒反応による微小粒子状物質(PM<sub>2.5</sub>)の活性酸素産生能の低減
- 光触媒反応による微小粒子状物質(PM[2.5])の活性酸素産生能の低減
- ヒカリ ショクバイ ハンノウ ニ ヨル ビショウリュウシジョウ ブッシツ(PM[2.5])ノ カッセイ サンソ サンセイノウ ノ テイゲン
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Description
Oxidative stress induced by fine particulate matter 2.5 (PM2.5) is a potential cause of adverse health effects due to production of reactive oxygen species (ROS). This study aimed to investigate effect of photocatalytic reaction on the oxidative potential (OP) of PM2.5 collected on TiO2 supporting quartz fibre filter. The OP of PM2.5 was measured by dithiothreitol assay coupled with a flow injection analysis. The results showed OP of PM2.5 collected in Kanagawa, Japan ranged from 0.18 to 0.31 nmol min-1 m-3 with a median of 0.21 nmol min-1 m-3 (n=9). After irradiating ultraviolet ray (UV) onto the surface of PM2.5 on the TiO2 filter for 3 days, the OP significantly reduced to 0.088 - 0.19 nmol min-1 m-3 with a median of 0.15 nmol min-1 m-3 (p=0.008). However, the reduction in OP was not monotonous; temporally increased at 5 days and then decreased with duration of UV irradiation. This suggests the ROS producing substances can be removed by the photocatalytic reaction, whilst OH radicals generated during UV-irradiation may produce the ROS producing substances, such as quinones from polycyclic aromatic hydrocarbons co-exiting in PM2.5 particles.
Journal
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- Indoor Environment
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Indoor Environment 22 (1), 15-22, 2019
Society of Indoor Environment, Japan
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Details 詳細情報について
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- CRID
- 1390564238095062656
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- NII Article ID
- 130007622350
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- NII Book ID
- AA11443020
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- ISSN
- 21864322
- 18820395
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- NDL BIB ID
- 029645981
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL Search
- Crossref
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed