Thermophysical Properties of Room Temperature Molten Salts Coexisting with Inorganic Powder

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  • MIZUHATA Minoru
    Department of Chemical Science & Engineering, Faculty of Engineering, Kobe University
  • ITO Yoshihiro
    Department of Chemical Science & Engineering, Faculty of Engineering, Kobe University
  • YASO Kazuo
    Department of Chemical Science & Engineering, Faculty of Engineering, Kobe University
  • DEKI Shigehito
    Department of Chemical Science & Engineering, Faculty of Engineering, Kobe University

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Description

<p>The differential scanning calorimetry was performed in order to discuss the thermochemical properties of room temperature molten salts (RTMSs) coexisting with porous inorganic powders such as α-Al2O3, ZrO2, SiO2, and SiC. Whereas the melting point of bulk sample was observed at 25.8°C, it decreased with an increase of the specific surface area of the solid phase. The molar enthalpy of fusion also decreased. It is suggested that the phase transition behavior is influenced by the coexistence of the porous solid phase.</p>

Journal

  • Electrochemistry

    Electrochemistry 73 (8), 603-605, 2005-08-05

    The Electrochemical Society of Japan

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