DEVELOPMENT OF SOLID OXIDE ELECTROLYSIS CELL CATHODES FOR DIRECT METHANATION IN CO2/H2O CO-ELECTROLYSIS

説明

Solid oxide electrolysis cells can produce syngas from H2O and CO2 by utilizing renewable energy-derived electricity (co-electrolysis). When operation temperature is lowered, methanation reaction occurs in cathode and direct methane synthesis will be realized. In this study, Ni-Ce0.9Gd0.1O1.95 cathode was impregnated by Ru, Co and Pd. From catalytic analyses, it was shown that hydrogen spillover from noble metals to adjacent Ni species played a role in enhancing CO2 methanation activity. In electrochemical tests, both CO2 conversion and CH4 selectivity increased along with applied potential. Cathode surface can be electron-rich under polarization, and that might affect the catalytic performance.

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詳細情報 詳細情報について

  • CRID
    1390564238115310080
  • NII論文ID
    130007609695
  • DOI
    10.24752/gre.1.0_225
  • ISSN
    24340871
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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