ハロゲン化炭化水素と金属類との反応性の研究(第2報) : 塩化シクロヘキシル,塩化ドデシルまたは塩化ブチルと各種の金属あるいは塩化金属との反応

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  • Studies on the Reactivity of Some Halogenohydrocarbons for Various Metals (II) : Reaction between Cyclohexyl Chloride, Dodecyl Chloride or Butyl Chloride and Many Sorts of Metals or Metallic Halides
  • ハロゲンカ タンカスイソ ト キンゾクルイ ト ノ ハンノウセイ ノ ケンキュウ 2

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type:Article

In the previous paper the reaction between benzyl halides and various metals was reported as the one of studies relating the additives for the halide catalysts. Now the similar studies using 3 sorts of chlorides are carried out and the following results are summarized. (1) It has been believed that in the previous report the first stage of this reaction is the formation of metallic halides initiated by the ionization of respective metal considering the relation between the induction period with each metal and thier electro-solution voltage, and the results now obtained further encourage this postulate. (2) It might be suggested that from the relation between the rate of reaction with each metallic halide and the electro-solution voltage of the metal contained in them, the second stage of this reaction is presumably the ionization of the metal accompanied by the capture of the halogen atom under the influence of the freshly produced metallic halides or other mechanism such as AlCl_2→AlCl^-_4. (3) Some proofs supporting the existence of few elementary reaction such as dehydro chlorination, hydrogenation and polymerization are shown by checking the properties of respective fraction from the reaction product related to dodecyl chloride and Al.

著者達の研究室では従来AlCl_3系触媒に各種の金属や無機塩類などを添加した際の影響を種々の反応について調べて来ているが，CCl_4のような多塩化物と金属アルミニウムとの反応の研究も行って来ている。これらと関連して前報ではハロゲン化ベンジルと各種金属との反応について行った実験の結果を報告しているので，これに引続いて副題の結果を報告するものである。

identifier:富山大学工学部紀要，15(1/2)

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