Photoaddition Reaction of Methyl 2,4-Dioxopentanoate with 1,3-Butadiene

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  • Photoaddition Reaction of Methyl 2 4 Di

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Abstract

The photoaddition reaction of methyl 2,4-dioxopentanoate with 1,3-butadiene gave isomeric dioxoesters, i.e., methyl 3- and 4-vinyl-2,4-dioxohexanoates and methyl 2-oxo-3-(2-oxopropyl)-Z-4-hexenoate, which is the first skeletally rearranged photoaddition products.

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