Condensation of Polyfluoroalkanols to Tropolone to Form 2-(Polyfluoroalkoxy)tropone and Their High-Pressure Diels-Alder Reaction with[60]Fullerene

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  • Condensation of Polyfluoroalkanols to Tropolone to Form 2-(Polyfluoroalkoxy) tropones and Their High-Pressure Diels-Alder Reaction with [60] Fullerene
  • Condensation of Polyfluoroalkanols to T

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説明

The Mitsunobu reaction of tropolone with 2-(perfluoroalkyl) ethanols, low-reactive nucleophiles, afforded 2-(polyfluoroalkoxy) tropones in good yields. The high-pressure (300MPa) Diels-Alder reaction of several 2-(polyfluoroalkoxy) tropones with C_<60> gave the [4+2] cycloadducts. Modification of the fullerene with polyfluoroalkoxylated homobarrelenone framework resulted in the great enhancement of solubility in common organic solvents.

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