Enhanced catalytic activity of H-β zeolite and MCM-41 in the cyclopentadiene Diels-Alder reactions
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- Imai Tomoyuki
- Department of Molecular and Material Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
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- Ono Fumiyasu
- Department of Molecular and Material Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
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- 田中 淳二
- 九州大学先導物質化学研究所
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- 佐野 庸治
- 広島大学大学院工学研究科
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- 金政 修司
- 九州大学先導物質化学研究所
書誌事項
- タイトル別名
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- Enhanced catalytic activity of H v zeolite and MCM 41 in the cyclopentadiene Diels Alder reactions
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The Diels-Alder cycloaddition reactions between cyclopentadiene and methacrolein are effectively catalyzed with the aluminum-modified mesoporous silica MCM-41 having a variety of metal cations in the pore such as Zn-,Co-,Ni- and La-MCM-41.The β zeolite (H-β)having protons in the pore shows a dramatically high catalytic activity in the same reaction to give a quantitative yield of cycloadducts at 0℃ in less than l h, and the dealuminated β zeolite is also a highly reactive catalyst.The Diels-Alder reactions of cyclopentadiene with 3-buten-2-one and 2-ethylacrolein are also activated with the H-β and Ni-MCM-41
収録刊行物
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- 九州大学大学院総合理工学報告
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九州大学大学院総合理工学報告 29 (4), 360-364, 2008-03
九州大学大学院総合理工学府
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詳細情報 詳細情報について
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- CRID
- 1390572174789875456
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- NII論文ID
- 120001280786
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- NII書誌ID
- AA1147319X
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- ISSN
- 13467883
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- DOI
- 10.15017/14590
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- HANDLE
- 2324/14590
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- NDL書誌ID
- 10198729
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- IRDB
- NDL
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可