Safety evaluation of PET bottles regenerated through mechanical recycling for use as liquid-seasoning and edible-oil containers

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  • Kondo Koichi
    Quality Assurance & Environmental Affairs Department, Mizkan Partners Co., Ltd.
  • Kozuka Rika
    Procurement Department, Mizkan Co., Ltd.
  • Kuwagaki Demmi
    Purchasing Department, Kikkoman Business Service Company
  • Takahashi Akihito
    Food Packaging Team, Process Development & Engineering Department, Product Development Division, Kikkoman Food Products Company
  • Nagano Manabu
    Food Processing Technology & Packages Department, Institute of Technology Solutions, R&D Division, Kewpie Corporation
  • Hirano Naomi
    Central Research Laboratory, Technical Division, The Nisshin OilliO Group, Ltd.
  • Hirosawa Ken
    Procurement Department, Mizkan Co., Ltd.
  • Sugiyama Ken-ichi
    Quality Assurance & Environmental Affairs Department, Mizkan Partners Co., Ltd.
  • Ozaki Asako
    Food Chemistry Section 2, Division of Hygienic Chemistry, Osaka Institute of Public Health

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  • 物理的再生法により製造された PET ボトルを液状調味料および食用油の容器に適用した場合の安全性評価

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Abstract

The safety of polyethylene terephthalate (PET) bottles regenerated through mechanical recycling (MR) for use as liquid-seasoning and edible-oil containers was evaluated through migration tests, as well as simulations using SML6 prediction software. MR-PET bottles were prepared from MR-PET pellets in which PET flakes intentionally contaminated with eight different surrogate contaminants and then regenerated in an actual MR process. The migration test conditions using the MR-PET bottles were set as follows: migration time of 5 months at 40°C (equivalent to the longest expiration date for seasonings and edible-oils of 2 years at 25°C), with 4% acetic acid, water, 20% ethanol, and heptane as the food simulants. The results showed that the concentrations of surrogate contaminants migrated into the food simulants were all below the migration limit of 10 ng/mL recommended by the Japanese Ministry of Health, Labor and Welfare (MHLW) in its guideline for the use of recycled plastic materials in food utensils, containers and packages. The simulation results under migration conditions of 2 years at 25°C and 5 months at 40°C predicted the migration amounts of surrogate contaminants to be well below the limit value of 10 ng/mL. The amount of antimony migrated to the aqueous food simulant (40°C, 4 months) was less than 10 ng/mL, which was less than the standard value of 50 ng/mL stated in the Food Sanitation Act. The results of this study confirm that MR-PET bottles fully satisfy the MHLW guideline and can be used safely as containers for liquid-seasonings and edible-oils.

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