O-22　バイオブタジエン合成を目的としたジメチルエーテルからの<i>n</i>-ブテン収率向上

DOI

書誌事項

タイトル別名
  • O-22　Improvement of <i>n</i>-Butene Yield from Dimethyl Ether for Bio-butadiene Synthesis

抄録

<p>Ferrierite zeolites were investigated as catalysts for the dimethyl ether (DME)-to-olefin (DTO) reactions to efficiently synthesize n-butene, such as 1-butene, trans-2-butene, and cis-2-butene using a fixed-bed flow reactor. P-loaded ferrierite zeolites with different structural parameters and acidic properties were prepared by the impregnation method by varying the P content and the temperature of air calcination as a pretreatment. Micropore surface area, external surface area, total pore volume, micropore volume, and weak and strong acid sites affected the DTO reaction behavior. A high n-butene yield (31.2 C-mol%) was observed, which is higher than the previously reported maximum yield (27.6 C-mol%).</p>

収録刊行物

詳細情報 詳細情報について

  • CRID
    1390579996560763904
  • DOI
    10.20550/jiebiomassronbun.19.0_47
  • ISSN
    24238341
    24238333
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
  • 抄録ライセンスフラグ
    使用不可

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