Electronic and Geometric Structures for Molecular Cluster Ions of Triatomic Molecules Investigated by Infrared Photodissociation Spectroscopy

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  • 総説
  • 3 ゲンシ ブンシ クラスター ナイ デ ノ ラジカルイオン ノ ソンザイ ケイタイ ノ ケンキュウ : セキガイコウ カイリ ブンコウ ニ モトズイテ
  • 3原子分子クラスター内でのラジカルイオンの存在形態の研究　～赤外光解離分光にもとづいて～

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Abstract

We apply infrared photodissociation (IRPD) spectroscopy in the 1000–3800 cm^–1 region for molecular cluster ions consisting of triatomic molecules such as CO_2 , CS_2 , OCS, and N_2O. The IRPD spectra show vibrational bands characteristic of ion core species and solvent molecules, which enables us to determine the electronic and geometric structures of radical ions in the clusters. On the basis of the IRPD results we examine the relation between the structures and properties of constituent molecules such as ionization energy, electron affinity, and molecular orbitals.

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