Synthesis of N-doped carbon with a high concentration of pyridinic N using a zeolite template method with pyridine as the deposition source

DOI Web Site 参考文献38件
  • Taniguchi Yurika
    Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University
  • Kokuryo Shinya
    Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University
  • Takada Ryuji
    Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University
  • Yang Xinran
    Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University
  • Miyake Koji
    Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University
  • Uchida Yoshiaki
    Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University
  • Nishiyama Norikazu
    Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University

抄録

<p>In recent years, N-doped carbon has emerged as an important electrode material because of its cost-effectiveness, high durability, and environmentally friendly characteristics. The catalytic activity of carbon atoms adjacent to nitrogen is contingent upon the position of nitrogen within the graphene lattice. Among various nitrogen species, pyridinic nitrogen is considered particularly effective in establishing an excellent active site for electrocatalytic applications. Nevertheless, achieving selective nitrogen doping poses challenges, given the high-temperature heat treatment required for carbon material synthesis. This study used pyridine, containing inherent pyridinic nitrogen with basicity, as the deposition source. The catalyst was synthesized using the zeolite template method, which allows adsorption on zeolite acid sites. The resulting catalysts showed a substantial presence of pyridinic N and high activity in oxygen reduction reactions (onset potential: 0.92 V vs. RHE).</p>

収録刊行物

  • Carbon Reports

    Carbon Reports 3 (1), 11-17, 2024-03-01

    炭素材料学会

参考文献 (38)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ