書誌事項
- タイトル別名
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- Remote Electronic Tuning for High-performance N-Heterocyclic Carbene Catalysis
説明
<p>One of the privileged motifs of chiral N-heterocyclic carbene (NHC) catalyst is an aminoindanol-derived structure, and many researchers achieved an improvement of this type of catalyst by introducing various substitutions at the triazolium nitrogen, which is located at the proximal site of the reactive carbene. Recently, we found that the introduction of substituents at the benzene ring of the indane moiety, which is far from the carbene carbon, could efficiently tune the catalytic activity of NHC catalysts in the enantioselective acylation of racemic alcohols, asymmetric intramolecular Stetter reactions, and intermolecular benzoin condensation of benzaldehyde derivatives. Herein, we report the development of novel high-performance NHC catalysts by remote substituent effects.</p>
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 82 (3), 222-233, 2024-03-01
公益社団法人 有機合成化学協会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390580848625407488
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- ISSN
- 18836526
- 00379980
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
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- 抄録ライセンスフラグ
- 使用不可
