INVESTIGATION OF THE STRUCTURE OF THE SOLIDIFIED MATERIAL IN THE HARDENING PROCESS OF PORTLAND CEMENT AND SODIUM SILICATE

  • YAMAZAKI Satoshi
    SHIZUOKA INSTITUTE OF SCIENCE AND TECHNOLOGY, Faculty of Science and Engineering, Department of Materials and Life Science(2200-2, Toyosawa, Fukuroi-shi, Shizuoka 437-0032, Japan)
  • NISHINO Hideki
    FUJI CHEMICAL Co., Ltd., Technical center(1683-1880, Nakagaito, Nasubigawa, Nakatsugawa-shi, Gifu 509-9132, Japan)
  • KUROIWA Daichi
    FUJI CHEMICAL Co., Ltd., Technical center(1683-1880, Nakagaito, Nasubigawa, Nakatsugawa-shi, Gifu 509-9132, Japan)

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Other Title
  • 普通ポルトランドセメントとけい酸ナトリウムとの硬化過程における固化体の構造の検討

Abstract

<p>We investigated the structure of solidified sodium silicate solidified with cement using Raman spectroscopy, X-ray diffraction measurements, and 29Si solid MAS NMR measurements. Raman spectroscopy and NMR measurements confirmed that alite was consumed in the early stage of the reaction, and sodium silicate promoted the reaction, resulting in an intermediate phase consisting of a chain structure containing Q2. Furthermore, X-ray diffraction halo analysis revealed the formation of an amorphous solid derived from tobermorite.</p>

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