Conformational Analysis for [M(dmso)<sub>6</sub>][BPh<sub>4</sub>]<sub>2</sub> [M=Co(II), Zn(II)] Showing Crystal-to-crystal Phase Transition

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  • SAKIYAMA Hiroshi
    Department of Science, Faculty of Science, Yamagata University, Kojirakawa 1-4-12, Yamagata 990-8560, Japan
  • MITSUHASHI Rjoji
    Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, Gakuen 2-1, Sanda 669-1337, Japan
  • MIKURIYA Masahiro
    Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, Gakuen 2-1, Sanda 669-1337, Japan
  • WAKI Katsushi
    Department of Science, Faculty of Science, Yamagata University, Kojirakawa 1-4-12, Yamagata 990-8560, Japan

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  • [M(dmso)<sub>6</sub>][BPh<sub>4</sub>]<sub>2</sub>錯体[M=Co(II), Zn(II)]の結晶相転移と配座解析

Abstract

<p>Based on the conformational analysis for an octahedral zinc(II) complex cation, [Zn(dmso)6]2+ (dmso: dimethylsulfoxide), the crystal-to-crystal phase transition behavior of [Co(dmso)6][BPh4]2 and [Zn(dmso)6][BPh4]2 was discussed.</p>

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