On the Electronic Nature of Bis((Z)-1-(benzo[d]oxazol-2-yl)-3.3.3-trifluoroprop-1-en-2-ate)palladium
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- May Kathleen L.
- Department of Chemistry & Biology, Ryerson University
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- Watanabe Genki
- Faculty of Pharmaceutical Sciences, Matsuyama University
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- Saijo Ryosuke
- Faculty of Pharmaceutical Sciences, Matsuyama University
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- Kawase Masami
- Faculty of Pharmaceutical Sciences, Matsuyama University
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- Gossage Robert A.
- Department of Chemistry & Biology, Ryerson University
書誌事項
- タイトル別名
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- On the Electronic Nature of Bis((<i>Z</i>)-1-(benzo[<i>d</i>]oxazol-2-yl)-3.3.3-trifluoroprop-1-en-2-ate)palladium
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<p>The electronic nature of the recently reported complex, bis((Z)-1-(benzo[d]oxazol-2-yl)-3.3.3-trifluoroprop-1-en-2-ate)palladium, is re-investigated by a combination of spectroscopy (NMR, IR, magnetic moment, etc.) and Density Functional Theory (DFT: B3LYP 6–31G*/LANL2DZ). In contrast to the recent report, the title complex displays all the properties of diamagnetism and hence retains the properties of a formally Pd(II) square planar complex with a bis-κ2-N,O-donor ligand set. A modified synthetic route is also presented which improves the yield of the compound.</p>
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 67 (5), 498-500, 2019-05-01
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390845713065234432
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- NII論文ID
- 130007641162
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- NII書誌ID
- AA00602100
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- ISSN
- 13475223
- 00092363
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- NDL書誌ID
- 029658578
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- PubMed
- 31061377
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可