Raman Spectroscopic Study of Ionic Association in Molten LaCl<sub>3</sub> and Molten CsCl-NaCl Mixtures
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- IWADATE Yasuhiko
- Graduate School of Science and Technology, Chiba University
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- MATSUURA Haruaki
- Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology
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- KAJINAMI Akihiko
- Department of Applied Chemistry, Faculty of Engineering, Kobe University
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- TAKASE Keiichi
- Graduate School of Science and Technology, Niigata University
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- OHTORI Norikazu
- Graduate School of Science and Technology, Niigata University
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- UMESAKI Norimasa
- Japan Synchrotron Radiation Research Institute
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- KOFUJI Hirohide
- Japan Nuclear Cycle Development Institute
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- MYOCHIN Munetaka
- Japan Nuclear Cycle Development Institute
Bibliographic Information
- Other Title
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- Raman Spectroscopic Study of Ionic Association in Molten LaCl3 and Molten CsCl-NaCl Mixtures
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Description
<p>The structures of molten LaCl3 and molten CsCl-NaCl mixtures were studied by Raman spectroscopy. Ionic association in these melts was discussed according to the information of vibrational modes. Complex species of the octahedral type, LaCl63−, was formed in the melt and no association was observed in the molten CsCl-NaCl system.</p>
Journal
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- Electrochemistry
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Electrochemistry 73 (11), 936-938, 2005-11-05
The Electrochemical Society of Japan
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Details 詳細情報について
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- CRID
- 1390845713071439232
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- NII Article ID
- 10016379315
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- NII Book ID
- AN00151637
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- ISSN
- 21862451
- 13443542
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- NDL BIB ID
- 7719050
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL Search
- Crossref
- CiNii Articles
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- Abstract License Flag
- Allowed