Electrochemical Behavior of Iron(II) Species in a Hydrophobic Room-temperature Molten Salt
-
- YAMAGATA Masaki
- Department of Applied Chemistry, Faculty of Science and Technology, Keio University
-
- TACHIKAWA Naoki
- Department of Applied Chemistry, Faculty of Science and Technology, Keio University
-
- KATAYAMA Yasushi
- Department of Applied Chemistry, Faculty of Science and Technology, Keio University
-
- MIURA Takashi
- Department of Applied Chemistry, Faculty of Science and Technology, Keio University
書誌事項
- タイトル別名
-
- Electrochemical Behavior of Iron 2 Species in a Hydrophobic Room temperature Molten Salt
この論文をさがす
説明
<p>The electrochemical behaviors of divalent iron species were investigated in a room-temperature molten salt (RTMS) consisting of 1-n-butyl-1-methylpyrrolidinium cation (BMP+) and bis(trifluoromethylsulfonyl)imide (TFSI−) anion. The TFSI−-salt of Fe(II) was soluble in BMPTFSI at room temperature. The cyclic voltammetric data for the Fe(III/Fe(II) processes at 1.1 V vs. Ag/Ag(I) showed quasi-reversible kinetics on a platinum electrode. The diffusion coefficient of Fe(II) determined by chronoamperometric techniques was 9.7 × 10−8 cm2 s−1 at 25°C. After cathodic reduction of Fe(II) at −2.0 V, furthermore, metallic Fe was electrodeposited on a copper substrate.</p>
収録刊行物
-
- Electrochemistry
-
Electrochemistry 73 (8), 564-566, 2005-08-05
公益社団法人 電気化学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390845713071447808
-
- NII論文ID
- 10015418514
-
- NII書誌ID
- AN00151637
-
- ISSN
- 21862451
- 13443542
-
- NDL書誌ID
- 7444879
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
-
- 抄録ライセンスフラグ
- 使用可