Determining the Coordination Number of Li<sup>+</sup> and Glyme or Poly(ethylene glycol) in Solution Using Attenuated Total Reflectance–Far Ultraviolet Spectroscopy
-
- UENO Nami
- Major in Science, Graduate School of Science and Engineering, Kindai University
-
- WAKABAYASHI Tomonari
- Department of Science, Faculty of Science and Engineering, Kindai University
-
- MORISAWA Yusuke
- Department of Science, Faculty of Science and Engineering, Kindai University
Bibliographic Information
- Other Title
-
- Determining the Coordination Number of Li⁺ and Glyme or Poly(ethylene glycol) in Solution Using Attenuated Total Reflectance-Far Ultraviolet Spectroscopy
Search this article
Description
<p>Attenuated total reflectance–far ultraviolet (ATR-FUV) spectra of Li+ and polyether ligands, such as glymes and poly (ethylene glycol) (PEG), in solution give information about changes in the electronic states of the ligands. From the ATR-FUV spectra, the coordination numbers between Li+ and monoglyme, diglyme, triglyme, and PEG400 were determined to be 4, 5, 6, and 5, respectively. Our results indicate that Li+ is coordinated only by the ligands rather than its counter-ions.</p>
Journal
-
- Analytical Sciences
-
Analytical Sciences 36 (1), 91-93, 2020-01-10
The Japan Society for Analytical Chemistry
- Tweet
Details 詳細情報について
-
- CRID
- 1390846609792160384
-
- NII Article ID
- 130007783846
-
- NII Book ID
- AA10500785
-
- ISSN
- 13482246
- 09106340
-
- NDL BIB ID
- 030213811
-
- PubMed
- 31866602
-
- Text Lang
- en
-
- Data Source
-
- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
-
- Abstract License Flag
- Disallowed