Determining the Coordination Number of Li⁺ and Glyme or Poly(ethylene glycol) in Solution Using Attenuated Total Reflectance-Far Ultraviolet Spectroscopy
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- UENO Nami
- Major in Science, Graduate School of Science and Engineering, Kindai University
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- WAKABAYASHI Tomonari
- Department of Science, Faculty of Science and Engineering, Kindai University
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- MORISAWA Yusuke
- Department of Science, Faculty of Science and Engineering, Kindai University
書誌事項
- タイトル別名
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- Determining the Coordination Number of Li<sup>+</sup> and Glyme or Poly(ethylene glycol) in Solution Using Attenuated Total Reflectance–Far Ultraviolet Spectroscopy
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説明
<p>Attenuated total reflectance–far ultraviolet (ATR-FUV) spectra of Li+ and polyether ligands, such as glymes and poly (ethylene glycol) (PEG), in solution give information about changes in the electronic states of the ligands. From the ATR-FUV spectra, the coordination numbers between Li+ and monoglyme, diglyme, triglyme, and PEG400 were determined to be 4, 5, 6, and 5, respectively. Our results indicate that Li+ is coordinated only by the ligands rather than its counter-ions.</p>
収録刊行物
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- Analytical Sciences
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Analytical Sciences 36 (1), 91-93, 2020-01-10
社団法人 日本分析化学会
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詳細情報 詳細情報について
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- CRID
- 1390846609792160384
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- NII論文ID
- 130007783846
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- NII書誌ID
- AA10500785
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- ISSN
- 13482246
- 09106340
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- NDL書誌ID
- 030213811
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- PubMed
- 31866602
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
- OpenAIRE
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- 抄録ライセンスフラグ
- 使用不可