次元交差領域における配位性ナノ材料の開発

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タイトル別名
  • Development of Coordination Nanomaterials Situated in Dimensional Crossover Region
  • Award Accounts 次元交差領域における配位性ナノ材料の開発
  • Award Accounts ジゲン コウサ リョウイキ ニ オケル ハイイセイ ナノ ザイリョウ ノ カイハツ

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<p>Coordination nanomaterials, which are made from a bottom-up assembly of metal ions and organic ligands, have been of particular interest to researchers because of their high degrees of structural designability and tunability based on substitutions of their structural components. In this review, successful fabrications and electronic and physical properties of mixed-valence multi-legged ladder complexes and crystalline oriented metal–organic framework (MOF) thin films, which straddle among one-, two-, and three-dimensional systems are described. Their unique electronic properties depending on the number of constituent legs and downsizing effects on physical properties have recently been overviewed.</p>

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