Chemistry of Pincer Complexes Possessing X-type Boron Ligand

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  • Morisako Shogo
    Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University
  • Yamashita Makoto
    Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University

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Other Title
  • X 型ホウ素配位子を有するピンサー錯体の化学

Abstract

<p>In this article, recent developments regarding the organometallic chemistry of boron-containing pincer ligands, especially in which a boron coordinated to transition metal center as an anionic σ-donor ligand, are reviewed. Boron-based pincer ligands can be subdivided into three main classes; diazaborole-, carborane-, and diarylboryl-ligand. All the papers relevant to such boron-based pincer ligands that have been published since 2009 are included in this review, which also summarizes applications of transitionmetal complexes bearing such boron-containing pincer ligands in catalytic and/or bond-cleavage reactions.</p>

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