A New Accelerated Durability Test Protocol for Water Oxidation Electrocatalysts of Renewable Energy Powered Alkaline Water Electrolyzers
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- ABDEL HALEEM Ashraf
- Yokohama National University
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- NAGASAWA Kensaku
- Yokohama National University
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- KURODA Yoshiyuki
- Yokohama National University
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- NISHIKI Yoshinori
- De Nora Permelec, Ltd.
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- ZAENAL Awaludin
- De Nora Permelec, Ltd.
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- MITSUSHIMA Shigenori
- Yokohama National University
抄録
<p>For electrocatalysts of oxygen evolution reaction (OER), a new accelerated durability test (ADT) protocol is presented. The protocol is designed to closely mimic the fluctuations of renewable energies. The unit cycle of the current ADT protocol represents the “ON/OFF” operation mode. In the “ON” step, the electrolyzer operates under a DC current of 0.6 A cm−2. In the “OFF” step, the electrocatalyst is subjected to a constant potential that is clearly more cathodic than its OER onset potential (namely, 0.3, 0.5, and 0.7 V vs. RHE) for 10 or 60 s. The transition from the “ON” state to the “OFF” state occurs through a cathodic linear sweep voltammetry of a fast sweep rate to mimic the sudden changes in the renewable power. A NiCoOx/Ni-mesh electrode was used as a case study. The electrode showed remarkable durability under continuous operation (i = 0.6 A cm−2) for about 900 hours. However, it did suffer severe degradation after a certain number of ADT cycles, and the rate of degradation mainly depends on the potential value and the duration of the “OFF” step. Interestingly, the inclusion of the 10-sec open-circuit potential step after the “ON” step clearly mitigates the impact of energy fluctuations on the durability of OER electrocatalysts.</p>
収録刊行物
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- Electrochemistry
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Electrochemistry 89 (2), 186-191, 2021-03-05
公益社団法人 電気化学会
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詳細情報
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- CRID
- 1390850247500148736
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- NII論文ID
- 130007995096
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- ISSN
- 21862451
- 13443542
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可