Redox reaction of a single ferrocene derivative observed by electrochemical scanning tunneling microscope
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- Kobayashi Yuzu
- RIKEN Department of Advanced Materials Science, School of Frontier Sciences, The University of Tokyo
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- Hong Misun
- RIKEN
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- Wong Raymond
- RIKEN
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- Yokota Yasuyuki
- RIKEN JST PRESTO
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- Takeya Jun
- Department of Advanced Materials Science, School of Frontier Sciences, The University of Tokyo
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- Kim Yousoo
- RIKEN
Bibliographic Information
- Other Title
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- 電気化学走査トンネル顕微鏡を用いたフェロセン誘導体単分子の酸化還元反応観測
Abstract
<p>The reactivity of redox reactions is greatly affected by the local structure of the electrode surface on a single-atom/single-molecular scale. Although it is strongly required to investigate the redox reactions on a molecular scale, the number of those reports is limited due to the difficulty of performing in situ measurement with high spatial resolution. In this study, redox reaction of a single ferrocene molecule was observed using an electrochemical scanning tunneling microscope (EC-STM), which is a combination of a scanning tunneling microscope (STM) and electrochemistry (EC). Using a tripod-type molecule as a base, we could stably deposit ferrocenes on the Au (111) electrode both in an isolated and dispersed state, which enables us to observe clear changes in the EC-STM images upon the redox reaction.</p>
Journal
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- Abstract book of Annual Meeting of the Japan Society of Vacuum and Surface Science
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Abstract book of Annual Meeting of the Japan Society of Vacuum and Surface Science 2021 (0), 3P09S-, 2021
The Japan Society of Vacuum and Surface Science
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Details 詳細情報について
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- CRID
- 1390853443031148928
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- NII Article ID
- 130008134206
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- ISSN
- 24348589
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed