Complexation and Fluorescence Behavior of Tris[(1-naphthoyloxy)ethyl]amine
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Tris[(1-naphthoyloxy)ethyl]amine (1) was found to display unique photophysical properties in the presence of the guest cations. The amine (1) revealed a broad emission band around 440nm that is typical of a structureless emission of a naphthoyl excimer and a naphthalene-amine exciplex. From the result of X-ray analysis, the amine (1) adopt a tripod conformation with crystallographic C_3 symmetry. Complexation of 1 with Al^<3+> increased the emission intensity of a factor by 5.3 in H_2O-CH_3OH (1:1 v/v).
収録刊行物
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- 九州大学機能物質科学研究所報告
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九州大学機能物質科学研究所報告 15 (1), 19-23, 2001
九州大学機能物質科学研究所
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詳細情報 詳細情報について
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- CRID
- 1390853649766487168
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- NII論文ID
- 110006177580
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- NII書誌ID
- AN10060378
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- ISSN
- 09143793
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- DOI
- 10.15017/7931
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- HANDLE
- 2324/7931
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- NDL書誌ID
- 5888759
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- IRDB
- NDL
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可